Cohesion
and surface tension
Cohesion is
the tendency of molecules of one substance to
hold together by mutual attraction. The hydrogen
bonding of water results in strong cohesive
forces. One effect of this is that the surface of
a drop of water will assume the smallest possible
area, and the drop therefore forms a sphere. The
water molecules at the surface are drawn in
towards the body of the drop forming a skin-like
layer of molecules at the surface. This force is
called surface tension. Insects walking on the
surface of water and the movement of water up
plants are two biological processes that can
occur as a result of the cohesive properties of
water molecules.
Adhesion
and capillarity
Adhesion is
the attraction of molecules of different
compounds to one another. The ability of water to
cling readily to other molecules is responsible
for the upward movement of water when a
small-bore tube is dipped into it. This
phenomenon is called capillarity. Xylem vessels
of a diameter 0.02mm can, in theory, support a
column of water of height 1.5m by capillarity
forces. One of its main biological effects is the
upward movement of water in the soil.
Thermal
capacity (specific heat)
Another
consequence of hydrogen bonding in water is that
much heat is needed to cause increased molecular
movement and hence gas (steam) formation. The
heat energy must first be used to break the
hydrogen bonds. For this reason the temperature
of water rises only very slowly for a given
amount of heat added, when compared with other
substances. Similarly it cools more slowly. In
all it is thermally stable and so biochemical
reactions in a water medium are not subjected to
large temperature fluctuations and can take place
at a more constant rate. Were it not for hydrogen
bonding, water would be a gas at normal
environmental temperatures and life as we know it
could not exist. For the same reasons much heat
is needed to evaporate water and therefore even
the evaporation of a small amount of water from
the surface of an organism has a large cooling
effect, e.g. sweating.
Density
Water has its
maximum density at 4ºC. Unlike most other
substances it is less dense as a solid than as a
liquid. It freezes from the top downwards and the
ice that forms at the surface can insulate the
warmer water below this layer from the colder
temperatures above it. This prevents large bodies
of water from freezing solid and has contributed
to the survival of aquatic organisms
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