|
Properties
Water (relative molecular
mass = 18) is a liquid at room temperature, in contrast with other
substances with small molecules such as methane (r.m.m. = 16), ammonia
(17), hydrogen sulphide (34) and carbon dioxide (44) which are gases.
In gases the molecules are widely spaced and free to move about
independently of each other, whereas in liquids the molecules are
close together. In water, the molecules are held close together
by hydrogen bonding. It is the hydrogen bonds that cause water to
exist as a liquid at the temperatures and pressures that normally
prevail on the Earth's surface. Life as we know it depends on this
property.
Water has a high heat capacity;
that is, a great deal of heat energy is required to raise the temperature
of water. This is because much of the energy is used to break the
hydrogen bonds which restrict the mobility of the molecules. As
a result, water is relatively slow to heat up or cool down. In fact,
the specific heat capacity of liquid water is the highest of any
known substance.
The latent heat (enthalpy)
of fusion of water (the heat energy needed to melt ice) is unusually
high. By the same token, relatively large amounts of heat energy
must be extracted from liquid water before it freezes. The latent
heat of vaporisation of water (the heat energy required to vaporise
liquid water) is also unusually high. Thus the evaporation of water
requires a great deal of energy and has a remarkable cooling effect.
Most liquids contract on cooling,
reaching their maximum density at their freezing point. Water is
unusual in reaching its maximum density above its freezing point
- at 4°C. So when water freezes the ice formed is less dense
than water and floats on top. Ice on the surface effectively insulates
the water below, thereby making it less likely that the bulk of
water (sea, pond or lake) will freeze up even if the air above is
very cold.
At the surface of water the
molecules are orientated so that most hydrogen bonds point inwards
towards other water molecules. This give water a very high surface
tension, higher than any other liquid except mercury. Despite this,
water molecules slide past each other relatively easily, and water
has a remarkably low viscosity.
Compared with other liquids,
water has extremely strong adhesive and cohesive properties that
prevent it breaking under tension. Water adheres strongly to most
surfaces, and can be drawn up through narrow tubes without the water
column breaking.
>>>next
|