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Pollution
The
nature of effluents
Water
pollution is most commonly associated with discharge of effluents
from sewers as sewage treatment plants, drains and factories. Outfalls
of this kind are known as 'point-source discharges'. Most cases
of accidental, negligent or illegal discharge are also from point
sources. The concentration of pollutant in the receiving water is
initially high decreasing as the distance from the point of discharge
increases. The effects of the pollution are therefore frequently
easy to observe. Some of the more serious forms pollution arise,
however, from 'diffuse' sources, that is the pollutant does not
enter the water from a single point. For example, in agricultural
areas, surface water runoff and groundwater infiltration onto lakes
and rivers can introduce plant nutrients (from fertilisers) and
pesticides in substantial quantities to water bodies. The effects
of pollution from diffuse sources can be serious, but are often
less immediately obvious than those from point sources as there
is no adjacent unpolluted area with which comparisons may be made.
Many pollutants also enter water through fallout from the atmosphere.
Historically, control and prevention of water pollution have concentrated
on point sources as these are more obvious, easily identifiable
and in theory easier to regulate at the point of origin. As awareness
has increased of the significance of diffuse sources of pollution,
control strategies have been under development but are based more
on the application of good practices designed to reduce pollutant
impact rather then on regulation of specific sources of input.
Most
effluents are complex mixtures of a large number of different harmful
agents. These include toxic substances of many kinds, extreme levels
of suspended solids, and dissolved and particulate putrescible organic
matter. In addition, many effluents are hot, of extreme pH value,
and normally contain high levels of dissolved salts.
Most
effluents also vary in their strength and composition, on a seasonal
diurnal or even hourly basis. Most sewage treatment plants report
regular diurnal peaks and thoughts in their output according to
patterns of water use. Sometimes storm-water drains are connected
to the sewerage system, so the strength of the sewage effluent will
vary with rainfall. Alterations in the strength and composition
of sewage also influence the efficiency of the sewage treatment
process, so that dilution of the influent does not necessarily cause
an improvement in the quality of the effluent. In industrial plants,
variations in the quality of the raw materials, or changes in specification
of the finished product, will require changes in the operating conditions
of the plant and lead to changes in the composition of the effluent.
Many industrial processes are 'batch' rather than continuous processes,
so that some effluent discharges will be intermittent rather than
continuous.
Organic
pollution
The
discharge of excessive quantities of organic matter is undoubtedly
the oldest, and even today the most widespread form of water pollution.
The
major sources of organic pollution are sewage and domestic waste;
agriculture (especially runoff from inadequately stored animal waste
and silage); various forms of food processing and manufacture; and
numerous industries involving the processing of natural materials
such as textile and paper manufacture. Most organic waste waters
contain a high proportion of suspended matter, and in part their
effects on the receiving water are similar to those of other forms
of suspended solid. However, the most important consequences of
organic pollution can be traced to its effect on the dissolved oxygen
concentration in the water and sediments. In unpolluted water, the
relatively small amount of dead organic matter is readily assimilated
by the fauna and flora. Some is consumed by detritivorous animals
and incorporated into their biomass. The remainder is decomposed
by bacteria and fungi, which are themselves consumed by organisms
at higher trophic levels. The activity of microorganisms results
in the breakdown of complex organic molecules to simple, inorganic
substances, such as phosphate and nitrate, carbon dioxide and water.
During these metabolic processes, oxygen is consumed. However, where
the organic load is light, the oxygen removed from the water is
readily replaced by photosynthesis and be re-aeration from the atmosphere.
Where
the input of organic material exceeds the capacity of the system
tm assimilate it, a number of changes take place. How far the sequence
of changes proceeds depends upon the severity of the organic load
and the physical characteristics of the receiving water. Initially,
the enhanced level of organic matter will stimulate increased activity
of the aerobic decomposer organisms. When their rate of oxygen consumption
exceeds the rate of re-aeration of the water, the dissolved oxygen
concentration in the water will fall. This alone may be sufficient,
as argued earlier, to eliminate some species, which may or may not
be replaced by others with less rigorous demands for oxygen. If
the drop in oxygen concentration is very severe, the aerobic decomposers
themselves will no longer be able to function, and anaerobic organisms
will become predominant.
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