Iridium, a chemical element, one of the platinum metals of
Group 8, of the periodic table. It is very dense and rare and is used in
platinum alloys. A precious, silver-white metal, it is hard and very brittle,
but it becomes ductile and can be worked at a white heat, from 1,200
degrees to 1,500 degrees Celsius. It is one of the densest terrestrial
substances. In the massive state the metal is practically unbreakable in
acids and is not attacked even by aquaregia. It can be dissolved in
concentrated hydrochloric acid in the presence of sodium perch lorate
at 125 degrees to 150 degrees Celsius.
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The element was discovered in 1802 in the acid-insoluble residues
of platinum ores by the English chemist Smithson Tennant. The name
iridium, comes from the Greek word iris "rainbow", refers to the
various colors of its compounds. Natural iridium consists of a mixture
of two stable isotopes. The chemistry of iridium centers on the
oxidation state, though compounds of all states from 0 to 6 are known
with perhaps the exception of +2. Iridium-containing ores are found in
South Africa, Alaska, USA, as well as in Myonnor (Buram), Brarit,
Russia, and Australia. In the late 20th century South Africa was the
world's major producer of the element iridium.
Because of difficulties in preparation and fabrication, the pure
metal has few applications. lridium is mainly, used in the form of
platinum alloys. Platinum-itidium alloys (5 to 10 percent iridium) are
already workable metals that are much harder and stiffer, and also more
resistant to chemical attack than the soft pure platinum. Such alloys are
used for jewelry, pen points, surgical pens, and electrical contacts and
sparking points.
It has a face-centered cubic crystalline structure.
The atomic number is 77, the atomic weight is 192.2, the
melting point is 2,410 degrees Celsius, the boiling point is 4,527
ceases, the specific gravity is 22.4. Pure iridium probably does not occur in
nature; its abundance in the earth's crust is very low, about 0.001 parts
per mmbw. Though very rare, iridium does occur in natural alloys with
other platnium metals. Iridium generally is produced commercially along
with the other platinum metals as a by-product of nickel of copper
production.
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