| Reactions
: Overview of Reactions with Water |
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There are three major types of reactions with water.
1. A PURE METAL or a METAL HYDRIDE react with water to
produce a BASE and HYDROGEN GAS (H2).
-
Metal hydride - A positive metal ion bonded to H with an
oxidation state
of -1
NOTE: The bases produced may be soluble and should be written
as their respective ions. See Solubility
Rules.
-
Sodium metal is added to distilled water.
-
Calcium metal is added to distilled water.
-
Solid calcium hydride is added to distilled water.
-
Solid lithium hydride is added to distilled water
2. A METAL OXIDE reacts with water to produce a
BASE.
-
Metal oxide - A positive metal ion bonded to O with an oxidation
state of -2. Metal oxides are called basic anhydrides because
they produce bases when they are added to water.
NOTE: There is no H present in a metal oxide, so no hydrogen
gas is produced.
NOTE: The bases produced may be soluble and should be written
as their respective ions. See Solubility
Rules.
-
Solid potassium oxide is added to water.
-
Solid barium oxide is added to water.
-
Solid lithium oxide is added to water.
-
Solid calcium oxide is added to water.
3. A NONMETAL OXIDE reacts with water to produce an
ACID.
-
Nonmetal oxide - A nonmetal with a positive oxidation state
bonded to O with an oxidation state of -2. Nonmetal oxides are called
acid anhydrides because they produce acids when they are added to
water.
NOTE: Strong acids dissociate nearly completely in water and
should be written as their respective ions. Weak acids dissociate only
slightly in water and should be written as a solid compound.
NOTE: When determining which acid will form where there is more
than one possibility (e.g. HNO2 or HNO3), the formula
of the acid formed can generally be found by adding up all the reactant atoms
and simplifying to the simplest whole-number ratio of atoms.
-
Solid dinitrogen pentoxide is added to water.
-
Carbon dioxide gas is bubbled through water.
-
Solid phosphorus (V) oxide is added to distilled water.
-
Sulfur dioxide gas is bubbled through water.
-
Sulfur trioxide gas is bubbled through water.
Next: "Overview of Acid-Base Reactions"