| Nuclear
Chemistry : Natural Versus Induced Radioactivity |
|
Natural Radiation
Three types of natural radioactivity exist:
-
Isotopes with half-lives longer than one billion years, e.g.
238U.
-
Daughter nuclides produced from the decay of these long-lived radioactive
nuclides, e.g. 234Th from alpha decay of 238U.
-
Nuclides that are still being produced as they decay, e.g.
14C.
-
The vast majority
(
80%) of stable nuclides have an even number of protons.
-
Most elements with an odd number of protons have only a single stable isotope.
-
Of the nuclides with an odd number of protons, nearly all
(
91%) have an even number of neutrons.
-
Nuclides with 2, 8, 20, 28, 50, 82, or 126 protons or neutrons are unusually
stable.
Radioactive nuclides with atomic numbers larger than 80 are grouped
into four categories:
 |
|
In the 4n series,
all nuclides have
atomic numbers
that are multiples
of 4. |
In the 4n + 1 series,
all nuclides have atomic
numbers that are one
number greater than
multiples of 4. |
|
 |
 |
|
In the 4n + 2 series,
all nuclides have atomic
numbers that are two
numbers greater than
multiples of 4. |
In the 4n + 3 series,
all nuclides have atomic
numbers that are three
numbers greater than
multiples of 4. |
|
 |
Induced Radiation
 |
-
First artificial radioactive isotope created by Irene Curie (daughter of
Pierre and Marie)
and Frederic Joliot in 1934.
-
They bombarded aluminum metal with alpha particles in the following reaction:
-
This reaction can also be written in the shorthand notation:

-
Where the target nuclide is separated from the daughter nuclide by
parentheses
in which the particle that hits the target and the particle that is released
are written.
|
-
Induced radiation reactions have extremely large activation energies which
can be overcome in linear accelerators or
cyclotrons.
- Artificial radiation can is also produced inside nuclear reactors which
contain thermal
neutrons.
Next: "Nuclear Fission"