| Nuclear
Chemistry : Ionizing Versus Nonionizing Radiation |
|
Excitation - Occurs when radiation excites an
electron from
an occupied
orbital into
an empty, higher energy orbital.
Ionization - Occurs when radiation carries enough
energy to completely remove an electron from an atom or molecule.
Ionizing Radiation - Radiation that carries more
than 1216 kJ/mol of energy.
-
e.g. UVB rays (higher end of the UV spectrum), x-rays, gamma
rays, cosmic rays.
Nonionizing Radiation - Radiation that carries less
than 1216 kJ/mol of energy.
-
e.g. radiowaves, microwaves, infrared, visible light, UVA
rays (lower end of the UV spectrum).
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1216 kJ/mol is the amount of energy required to remove an electron from
a water molecule.
-
The division between ionizing and nonionizing radiation is split above and
below 1216 kJ/mol because living tissue is mostly made up of water (70-90%
by weight)
How Water Becomes Ionized
-
When water is ionized and an electron is lost, H2O+
ions are produced:
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H2O+ is an example of a free radical.
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Free Radical - Extremely reactive particle that
contains an unpaired valence-shell electron.
-
H2O+ is so reactive (very strong oxidizing agent)
that it can remove electrons or hydrogen atoms from molecules in the cell.
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Much larger amounts of nonionizing radiation would be required to
equal the strength of a very small amount of ionizing radiation.
Three ways to measure ionizing radiation
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Measure the activity of the source in curies
(disintegrations/sec) - EASIEST
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Measure the radiation to which an object is exposed in
roentgens by measuring the amount of radiation produced when this
radiation passes through a sample of air.
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Measure the radiation absorbed by the object in radiation absorbed
doses (rads) - HARDEST but most useful.
-
rad = absorption of 10-5 J of energy per gram of body
weight
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Cells become inactivated at 100 rads.
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Fatal level is 400-450 rads.
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Radiation biological effectiveness (RBE) - corrects
for the rate at which radiation passes through the tissue.
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Roentgen equivalent man (rem) - The product of the
absorbed does (rads) and the biological effectiveness (RBE).
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Next: "Natural Versus Induced Radiation"