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Chemical Kinetics - The study of the rates of chemical
reactions.
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Rate of a Reaction - The change in concentration
of one of the reactants (DX), during a given period
of time (Dt)
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The reaction rate gradually decreases as reactants are consumed.
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Instantaneous Rate of Reaction - The rate of a reaction
at an instant in time.
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where d(X)/dt is the derivative X/t in terms of t.
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Rate Law - An equation that describes how the rate
of a chemical reaction depends on the concentrations of the reactants consumed
in that reaction.
rate = k[O3]
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Rate Constant (k) - The proportionality constant
in the rate law equation that describes the relationship between the
rate of a step in a chemical reaction and the product of the concentrations
of the reactants consumed in that step.
**The rate law for a reaction cannot be determined by the coefficients
of the balanced reaction; it must be determined experimentally.
For gas equilibrium equations, the equilibrium constant (Kc) is
equal to the rate constant for the forward reaction divided by the rate constant
of the reverse reaction.
See Sample Rate Calculations
For the reaction:
where a, b, c, d are the coefficients for the reactants and products A, B,
C, D
Next: "Order and Molecularity"