Gases :  Laws


Boyle's Law
  • The Pressure (P) of a gas is inversely proportional to Volume (V) at constant
    Temperature (T) and moles of gas (n).

Robert Boyle
  • The product of pressure and volume of one measurement is equal to the product
    of the pressure and volume of another measurement.


Amonton's Law

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Charles' Law

  • The Volume of a gas is directly proportional to the Temperature (Kelvin)
    at constant P and n.

Jacques-Alexandre-
César Charles

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Gay-Lussac's Law  (law of combining volumes)

  • The ratio of the volumes of gases consumed or produced in a chemical reaction is
    equal to the ratio of simple whole numbers (coefficients in the balanced equation).
    • e.g.  Carbon monoxide combines with oxygen in a 2:1 ratio by volume  

             

Joseph Louis
Gay-Lussac


Avogadro's Hypothesis
  • The Volume of a gas is directly proportional to the moles of the gas, n at constant P and T.

  • The hypothesis that equal volumes of different gases at the same temperature
    and pressure contain the same number of particles.
Amadeo Avogadro


Dalton's Law of Partial Pressures
  • The total pressure of a mixture of gases is equal to the sum of the partial pressures of the various components.
  • Partial Pressure - The fraction of the total pressure of a mixture of gases that results from one component of the mixture.

  • This Law can be used to correct the amount of water vapor picked up when a gas is collected by displacing water.

    • Vapor Pressure - The pressure of the gas that collects above a liquid in a closed container.
John Dalton

Next:  "Ideal Gas Equation"