| Acids and Bases : pH |
1909 - S. P. L. Sørenson - Danish biochemist who suggested the use of a logarithmic scale to express the concentration of the H3O+ ion
pH - The negative of the log of the H3O+ (hydronium) ion concentration:
pOH - The negative of the log of the OH- (hydroxide) concentration:
Water-dissociation equilibrium constant
(Kw) - The product of the
equilibrium concentration of the H3O+ and
OH- ions in an aqueous solution is
equal to 1.00 x 10-14 at
25
C:
When the logs of both sides are taken:
NOTE: When the pH is doubled, the [H3O+
] decreases by a factor of 100.
When the pH is quadrupled, the [H3O+ ] decreases
by a factor of 10,000
A substance is acidic if the pH is less than 7.
A substance is basic if the pH is greater than 7.
A substance is neutral if the pH is equal to 7.
In pure water, the concentration of the hydronium and hydroxide ions are
equal. At
25
C:
Relationship Between[H3O+] and
[OH-]
with pH and pOH of an Aqueous Solution
| [H3O+] (M) | [OH-] (M) | pH | pOH | ||||
| 1.0 | 1.0 x 10-14 | 0 |
14 |
||||
| 1.0 x 10-1 | 1.0 x 10-13 | 1 |
13 |
||||
| 1.0 x 10-2 | 1.0 x 10-12 | 2 |
12 |
||||
| 1.0 x 10-3 | 1.0 x 10-11 | 3 |
11 |
||||
| 1.0 x 10-4 | 1.0 x 10-10 | 4 |
10 |
||||
| 1.0 x 10-5 | 1.0 x 10-9 | 5 |
9 |
||||
| 1.0 x 10-6 | 1.0 x 10-8 | 6 |
8 |
||||
| 1.0 x 10-7 | 1.0 x 10-7 | 7 |
7 |
Neutral |
|||
| 1.0 x 10-8 | 1.0 x 10-6 | 8 |
6 |
||||
| 1.0 x 10-9 | 1.0 x 10-5 | 9 |
5 |
||||
| 1.0 x 10-10 | 1.0 x 10-4 | 10 |
4 |
||||
| 1.0 x 10-11 | 1.0 x 10-3 | 11 |
3 |
||||
| 1.0 x 10-12 | 1.0 x 10-2 | 12 |
2 |
||||
| 1.0 x 10-13 | 1.0 x 10-1 | 13 |
1 |
||||
| 1.0 x 10-14 | 1.0 | 14 |
0 |
pH of 0.1 M Solutions of Common Acids and Bases
|
|
Acid-base indicator - A weak acid or weak base which changes color when it gains or loses an H+ ion.
Examples of Acid-Base Indicators
Indicator |
pH Range |
Color Change |
||
| Methyl violet Thymol blue Bromophenol blue Methyl orange Methyl red Litmus Bromocresol purple Bromophenol red Bromothymol blue Cresol red Thymol blue Phenolphthalein Alizarin yellow |
0.0 - 1.6 1.2 - 2.8 3.0 - 4.6 3.2 - 4.4 4.4 - 6.2 5 - 8 5.2 - 6.8 5.2 - 6.8 6.2 - 7.6 7.2 - 8.8 8.0 - 9.6 8.0 - 10.0 10.0 - 12.0 |
yellow
red yellow red red pink yellow yellow yellow yellow yellow colorless yellow |
Next: "Factors that Affect the Relative Strengths of Acids and Bases"