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Unsaturated compounds


Unsaturated compounds are compounds in which carbon atoms are joined together by double or triple bonds.

Alkenes
Organic compounds with a double bond between the carbon atoms are members of the Alkene family of Organic compounds. The Alkenes are more reactive than the Alkanes (Alkanes are saturated compounds. They have a single bond between carbon atoms) as the double bond is capable of 'opening up' and bonding with other elements or compounds through an addition reaction.

The test for the double bond is Bromination, i.e. the addition of Bromine water. When testing the gas ethane for the double bond, bromine water is added to a test tube of the gas. The red bromine water turns colourless. This is a positive result indicating a double bond.

The reaction proceeds as follows:

  • The bromine water is added...
  • ...the double bond swings open to accept the bromine atoms...
  • ...the bromine atoms take up a position.

This type of reaction is called an addition reaction

Other examples of the Alkenes are:

  • Ethene
  • Prop-1-ene
  • But-1-ene
  • Pent-1-ene

The "1" in their names is because the double bond is on the 1st carbon atom.


Alkynes
Alkynes are organic compounds which contain a triple bond between the carbon atoms. They are very reactive and volatile and like the Alkenes undergo addition reactions and decolourise bromine water. A common example, Ethyne (Industrially know as Acetylene), burns in oxygen at a very high temperature and is used for cutting and welding steel.

Other Examples:

  • Ethyne
  • Prop-1-yne
  • But-1-yne
  • Pent-1-yne


It should be noted that the Alkanes, Alkenes and Alkynes are all closely related.



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