Uncertainty
Principle In quantum
theory, the principle that it is impossible to
precisely specify certain quantities simultaneously.
The position and momentum of a particle, such as an
electron, form one such pair. Classically one could,
in principle, observe that a particle had passed
through an exactly specified position, moving with a
precise momentum. This is not possible in quantum
mechanics.
The uncertainty principle was discovered
by the German physicist Werner Heisenberg in 1927. He
realized that measuring the position of an elementary
particle alters its momentum in a random manner, and
vice versa. Heisenberg considered an electron that
has a definite, known momentum and that passes under
a powerful microscope. The electron's position can be
measured at a given moment by shining light on to it
and observing the light that it reflects. This
technique allows the position to be specified with an
accuracy comparable to the wavelength of light used.
However, when the photons ("particles" of light) are
scattered from the electron, they alter its momentum,
because the photons have a momentum of their own. The
observer cannot calculate the extent of this
disturbance, which is random.
Increasing the wavelength
decreases the disturbance, because photons of longer
wavelength have less momentum. However, increasing
the wavelength reduces the precision of the position
measurement. Decreasing the wavelength allows better
position measurement, but increases the disturbance
to the momentum.
The principle that measurement disturbs
that which is being measured was already well
established in science. What was so radical about
Heisenberg's discovery was that this quantum
disturbance could not be compensated for. Heisenberg
calculated that the product of the uncertainty in
position and the uncertainty in momentum is never
less than an amount involving h, which is Planck's
constant, named after the German physicist Max
Planck. If Dp is the uncertainty in a particle's
momentum and Dx the uncertainty in its position
then:
Dp × Dx ³ h / 4p
implying that, as one quantity is measured more
precisely, the other must get more uncertain. It is
impossible to specify both exactly, as h has a
non-zero, although very small, value, equal to 6.62
× 10-34 joule-seconds.
Reaction to the
announcement of the uncertainty principle was
initially mixed. The Danish physicist Niels Bohr, one
of the founders of quantum theory, immediately
grasped its importance, but differed with Heisenberg
as to the interpretation of the idea. To Bohr the
uncertainty principle did not describe an inability
of physicists to measure quantities, but a limitation
of the way in which momentum and position could be
defined. Bohr felt that physical quantities were
defined by the experiments that measured them-they
were not properties possessed independently by
particles in themselves. In other words, when an
electron's position is measured with light that
disturbs its momentum, it is not that the electron
has a well-defined momentum of which we are
ignorant-rather, the electron does not have a
well-defined momentum under those conditions.
This idea was unacceptable
to Albert Einstein, who deeply believed in the
independent reality of the laws of physics. To him it
was nonsense to say that such a property was defined
by the way in which scientists measure it. A vigorous
debate between Bohr, Heisenberg, and Einstein
followed. In the end Einstein was forced to admit
that quantum theory was logically consistent, but he
always hoped that it would be replaced by a new
theory. To date quantum theory has been tested in a
variety of experiments of increasing precision and
has always been shown to provide a full account of
the experimental results.
The uncertainty principle
extends to other "complementary" quantities as well,
such as energy and time. If the energy of a particle
is measured over a time period (Dt), the uncertainty
in energy (DE) is related to the duration of the
measurement:
DE × Dt ³ h / 4p
Bohr extended the idea of complementarity to include
concepts outside physics. For example, he suggested
that a description of a living creature in biological
terms was complementary to a description in physical
terms: to know all about the inner workings of the
organism would require taking it to pieces, which
would kill it. Many other thinkers have commented on
parallels between quantum mechanics and ideas of
Eastern mysticism.
Wave-Particle
Duality Possession of
both wave-like and particle-like properties by
subatomic objects. The fundamental principle of
quantum theory is that an entity that we are used to
thinking of as a particle (such as an electron) can
behave like a wave, while entities that we are used
to thinking of as waves, such as light waves, can
also be described in terms of particles (in this
case, photons).
This wave-particle duality
is most clearly seen in "double-slit" experiments, in
which either electrons or photons are fired, one at a
time, through a pair of holes in a barrier, and
detected on a screen (like a TV screen) on the other
side. In both cases, particles leave the gun on one
side of the barrier and arrive at the detector
screen, each making an individual spot on the screen.
However, the overall pattern that builds up on the
screen as more and more particles are fired through
the two holes is an interference pattern, made up of
light and dark stripes, which can only be explained
in terms of waves passing through both holes in the
barrier and interfering with each other. This gives
rise to the aphorism that quantum entities "travel as
waves but arrive as particles".
Wave-particle duality is
also related to the uncertainty principle. This says
that the exact position of a particle and its exact
momentum (essentially, its speed and direction of
movement) can never be known simultaneously. Position
is a particle property-particles exist at a point.
Waves are extended entities by nature, which do not
have a position, although they do have momentum.
Entities that are both wave and particle are never
quite sure either where they are or where they are
going.
The wavelength l and momentum p of a quantum entity
are related by the equation pl =
h, where h is a constant known as Planck's
constant.
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