Nuclear
Energy
Energy released during the splitting or
fusing of atomic nuclei. The quantities of energy
that can be obtained from the nucleus far exceed
those that can be obtained from chemical processes,
which involve only the outer regions of the
atom.
The energy of any system,
whether physical, chemical, or nuclear, is manifested
by its ability to do work or to release heat or
radiation. The total energy in a system is always
conserved, but it can be transferred to another
system or changed in form.
Until about 1800 the principal fuel was wood, its
energy derived from solar energy stored in plants
during their lifetimes. Since the Industrial
Revolution, people have depended on fossil fuels-coal
and petroleum-also derived from stored solar energy.
When a fossil fuel such as coal is burned, atoms of
hydrogen and carbon in the coal combine with oxygen
atoms in air; water and carbon dioxide are produced
and heat is released, equivalent to about 1.6
kilowatt-hours per kilogram or about 10 electron
volts (eV) per atom of carbon. This amount of energy
is typical of chemical reactions, which result from
changes in the electronic structure of the atoms. A
part of the energy released as heat keeps the
adjacent fuel hot enough to keep the reaction
going.
The Atom
The atom consists of a small,
massive, positively charged core (nucleus) surrounded
by electrons. The nucleus, containing most of the
mass of the atom, is itself composed of neutrons and
protons bound together by very strong nuclear forces,
much greater than the electrical forces that bind the
electrons to the nucleus. The mass number of a
nucleus is the number of nucleons, or neutrons and
protons, it contains; the atomic number is the
number of positively charged protons.
The binding energy of a
nucleus is a measure of how tightly its neutrons and
protons are held together by the nuclear forces. The
binding energy per nucleon, the energy required to
remove one neutron or proton from a nucleus, is a
function of the mass number A. The curve of binding
energy implies that if two light nuclei coalesce to
form a heavier nucleus, or if a heavy nucleus splits
into two lighter ones, more tightly bound nuclei
result, and energy will be released.
Nuclear energy, measured
in millions of electron volts (MeV), is released by
the fusion of two light nuclei, as when two heavy
hydrogen nuclei, deuterons, combine in the reaction
producing a helium-3 nucleus, a free neutron, and 3.2
MeV, or 5.1 × 10-13 J. Nuclear energy
is also released when the fission of a heavy nucleus
such as U is induced by the absorption of a neutron,
as in producing caesium-140, rubidium-93, three
neutrons, and 200 MeV, or 3.2 × 10-11
J. A nuclear fission reaction releases 10 million
times as much energy as is released in a typical
chemical reaction.
21H +
21H ------>
32He +
10n +3.2
Mev
Nuclear Energy from
Fission
10n +
23592U ----->
14055Cs +
9337Rb +3 10n
+200 Mev
The two key
characteristics of nuclear fission important for the
practical release of nuclear energy are both evident
in equation above. First, the energy per fission is
very large. In practical units, the fission of 1 kg
(2.2 lb) of uranium-235 releases 18.7 million
kilowatt-hours as heat. Second, the fission process
initiated by the absorption of one neutron in
uranium-235 releases about 2.5 neutrons, on the
average, from the split nuclei. The neutrons released
in this manner quickly cause the fission of several
more atoms, thereby releasing four or more additional
neutrons and initiating a self-sustaining series of
nuclear fissions, a chain reaction, which results in
continuous release of nuclear energy.
Naturally occurring
uranium contains only 0.71 per cent uranium-235; the
remainder is the non-fissile isotope uranium-238. A
mass of natural uranium by itself, no matter how
large, cannot sustain a chain reaction because only
the uranium-235 is easily fissionable. The
probability is rather low that a neutron produced by
fission, having an initial energy of about 1 MeV,
will induce fission, but can be increased by a factor
of hundreds when the neutron is slowed down through a
series of elastic collisions with light nuclei such
as hydrogen, deuterium, or carbon. This fact is the
basis for the design of practical energy-producing
fission reactors.
In December 1942, at the
University of Chicago, the Italian physicist Enrico
Fermi succeeded in producing the first nuclear chain
reaction. This was done with an arrangement of
natural uranium lumps distributed within a large
stack of pure graphite, a form of carbon. In Fermi's
"pile", or nuclear reactor, the graphite moderator
served to slow the neutrons and make a chain reaction
possible.
Nuclear Fusion
The release of nuclear energy
can occur at the low end of the binding energy curve
through the coalescence of two light nuclei into a
heavier one. The energy radiated by the Sun arises
from such fusion reactions deep in its interior. At
the enormous pressures and temperatures existing
there, hydrogen nuclei combine in a series of
reactions equivalent to equation:
21H +
21H ------>
32He +
10n +3.2
Mev
and give rise to most of the energy
released by the Sun. Other reactions lead to the same
result in stars more massive than the Sun.
Artificial nuclear fusion
was first achieved in the early 1930s by bombarding a
target containing deuterium, the mass-2 isotope of
hydrogen, with high-energy deuterons (deuterium
nuclei) in a cyclotron. To accelerate the deuteron
beam a great deal of energy was required, most of
which appeared as heat in the target. As a result, no
net useful energy was produced. In the 1950s the
first large-scale but uncontrolled release of fusion
energy was demonstrated in the tests of thermonuclear
weapons by the United States, the USSR, Great
Britain, and France. Such a brief and uncontrolled
release cannot be used for the production of electric
power.
In the fission reactions
discussed earlier, the neutron, which has no electric
charge, can easily approach and react with a
fissionable nucleus-for example, uranium-235. In the
typical fusion reaction, however, the reacting nuclei
both have a positive electric charge, and the natural
repulsion between them, called Coulomb repulsion,
must be overcome before they can join. This occurs
when the temperature of the reacting gas is
sufficiently high-50 to 100 million ° C (90 to
180 million ° F). In a gas of the heavy hydrogen
isotopes deuterium and tritium at such a temperature,
the fusion reaction occurs, releasing about 17.6 MeV
per fusion event. The energy appears first as kinetic
energy of the helium-4 nucleus and the neutron, but
is soon transformed into heat in the gas and
surrounding materials.
If the density of the gas
is sufficient-and at these temperatures the density
need be only 10-5 atmospheres, or almost a
vacuum-the energetic helium-4 nucleus can transfer
its energy to the surrounding hydrogen gas, thereby
maintaining the high temperature and allowing a
fusion chain reaction to take place. Under these
conditions, "nuclear ignition" is said to have
occurred.
The basic problems in attaining useful
nuclear fusion conditions are (1) to heat the gas to
these very high temperatures, and (2) to confine a
sufficient quantity of the reacting nuclei for a long
enough time to permit the release of more energy than
is needed to heat and confine the gas. A subsequent
major problem is the capture of this energy and its
conversion to electricity.
At temperatures above
100,000° C (180,000° F), all the hydrogen
atoms are fully ionized. The gas consists of an
electrically neutral assemblage of positively charged
nuclei and negatively charged free electrons. This
state of matter is called a plasma.
A plasma hot enough for
fusion cannot be contained by ordinary materials. The
plasma would cool very rapidly, and the vessel walls
would be destroyed by the temperatures present.
However, since the plasma consists of charged nuclei
and electrons, which move in tight spirals around
strong magnetic field lines, the plasma can be
contained in a properly shaped magnetic field
region.
In any useful fusion
device, the energy output must exceed the energy
required to confine and heat the plasma. This
condition can be met when the product of confinement
time t and plasma density n exceeds about
1014. The relationship t n
>- 1014 is called the
Lawson criterion.
Numerous schemes for the
magnetic confinement of plasma have been tried since
1950 in the United States, the former USSR, Great
Britain, Japan, and elsewhere. Thermonuclear
reactions have been observed, but the Lawson number
rarely exceeded 1012. One device,
however-the tokamak, originally suggested in the USSR
by Igor Tamm and Andrey Sakharov-began to give
encouraging results in the early 1960s.
The confinement chamber of a tokamak has
the shape of a torus, with a minor diameter of about
1 m (about 3.3 ft) and a major diameter of about 3 m
(about 9.8 ft). A toroidal magnetic field of about 5
tesla is established inside this chamber by large
electromagnets. This is about 100,000 times the
Earth's magnetic field at the planet's surface. A
longitudinal current of several million amperes is
induced in the plasma by the transformer coils that
link the torus. The resulting magnetic field lines
are spirals in the torus, and confine the plasma.
Following the successful
operation of small tokamaks at several laboratories,
two large devices were built in the early 1980s, one
at Princeton University in the United States and one
in the USSR. In the tokamak, high plasma temperature
naturally results from resistive heating by the very
large toroidal current, and additional heating by
neutral beam injection in the new large machines
should result in ignition conditions.
Another possible route to
fusion energy is that of inertial confinement. In
this technique, the fuel-tritium or deuterium-is
contained within a tiny pellet that is bombarded on
several sides by a pulsed laser beam. This causes an
implosion of the pellet, setting off a thermonuclear
reaction that ignites the fuel. Several laboratories
in the United States and elsewhere are currently
pursuing this possibility. Progress in fusion
research has been promising, but the development of
practical systems that produce more power than they
consume will probably take decades to realize. The
research is expensive, as well.
However, some progress has
been made in the early 1990s. In 1991, for the first
time ever, a significant amount of energy-about 1.7
million watts-was produced from controlled nuclear
fusion at the Joint European Torus (JET) Laboratory
in England. In December 1993, researchers at
Princeton University used the Tokamak Fusion Test
Reactor to produce a controlled fusion reaction that
output 5.6 million watts. However, both JET and the
Tokamak Fusion Test Reactor consumed more energy than
they produced during their operation.
If fusion energy does
become practicable, it offers the following
advantages: (1) a limitless source of fuel, deuterium
from the ocean; (2) no possibility of a reactor
accident, as the amount of fuel in the system is very
small; and (3) waste products much less radioactive
and simpler to handle than those from fission
systems.
The Chain
Reaction
When the uranium nucleus
fissions, it breaks up into a pair of nuclear
fragments and releases energy. At the same time, the
nucleus emits very quickly a number of fast neutrons,
the same type of particle that initiated the fission
of the uranium nucleus. This makes it possible to
achieve a self-sustaining series of nuclear fissions;
the neutrons that are emitted in fission produce a
chain reaction, with a continuous release of
energy.
The light isotope of
uranium, uranium-235, is easily split by the fission
neutrons and, upon fission, emits an average of about
2.5 neutrons. One neutron per generation of nuclear
fissions is necessary to sustain the chain reactions.
Others may be lost by escape from the mass of
chain-reacting material, or they may be absorbed in
impurities or in the heavy uranium isotope,
uranium-238, if it is present. Any substance capable
of sustaining a fission chain reaction is known as a
fissile material.
Atomic Bomb
Extremely powerful
explosive weapon whose force is fuelled by the
splitting, or fission, of the nuclei of specific
isotopes of uranium or plutonium (uranium-235,
uranium-238, and plutonium-239) in a chain
reaction.
The process of fission
releases enormous energy in the form of extreme heat
and a massive shock wave. A slow, carefully
controlled fission reaction generates power for
electricity companies worldwide, but in an atomic
bomb the release of energy continues unabated until
all fissile material is exhausted. In addition to its
virtually limitless destructive effects-flash burns,
and widespread destruction through pressure waves,
and high winds-a nuclear explosion also produces
deadly radiation in the form of gamma rays and
neutrons, which destroy living matter and contaminate
soil and water.
Fission and
Fusion
Atomic bombs are nowadays
called nuclear weapons, which are of two general
types: fission or fusion. Fission weapons were the
first atomic bombs to be developed, tested, and used
in war, when the United States dropped two atomic
bombs on Hiroshima and Nagasaki in Japan in 1945, at
the end of World War II.
Fusion bombs, also called
hydrogen or thermonuclear bombs, are vastly more
powerful than fission bombs. They were developed and
tested in the early 1950s, but these have never been
used in warfare. A thermonuclear device depends on a
fission reaction to produce extreme heat that causes
hydrogen isotopes of deuterium and tritium to come
together, or fuse. This process yields energy many
times greater than that of fission-type devices. Most
nuclear weapons in present-day stockpiles are
thermonuclear devices.
Development of the
First Atomic Bombs
In the late 1930s, physicists
in Europe and the United States realized that, in
theory, the fission of uranium could be used to
create an extremely powerful explosive weapon. In
August 1939, the physicist Albert Einstein sent a
letter to US President Franklin D. Roosevelt that
described this possibility and warned of its
potential development by other nations.
The US government explored
this possibility for several years before
establishing in 1942 the top-secret Manhattan
Project, under the directorship of US Army
Brigadier-General Leslie Groves. This team, working
in several locations but in large part at Los Alamos,
New Mexico, under the scientific leadership of
physicist J. Robert Oppenheimer, designed and built
the first atomic bombs, based on uranium-235 and on
the more experimental plutonium-239.
The first atomic explosion
was conducted, as a test code-named Trinity, of the
plutonium bomb. It was carried out near Alamogordo,
New Mexico, at dawn on July 16, 1945. The energy
released from this explosion was equivalent to that
released by the detonation of 20,000 tons of
trinitrotoluene (TNT). The United States dropped the
first atomic bomb on the Japanese city of Hiroshima
on August 6. It followed with a second against
Nagasaki on August 9. As many as 100,000 people were
killed by the Hiroshima uranium device, called Little
Boy, and some 40,000 by the Nagasaki plutonium bomb,
called Fat Man. Japan agreed to US terms of surrender
on August 14.
These are the only times
that a nuclear weapon has ever been used in a
conflict between nations. Since then, several nations
have exploded nuclear devices in tests, in the
atmosphere, under the earth, and under the sea. Only
the United States, Russia, Britain, France, and China
admit to possessing nuclear weapons. Other nations,
such as Israel and India among others, are also
thought to have them, or to be able to assemble them
quickly.
|