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types of solutions
You may be asking yourself why solutions are
necessary. Well, they serve a lot of practical purposes. For
instance, most chemical reactions are run in solution. Solutions
also usually have a lower melting and freezing point than just a
substance by itself.
Let's say that we have a handful of salt crystals,
NaCl. When this salt dissolves in water, there is a uniform
dispersion of ions in this water. What we have just formed is
called a solution. A solution is defined as a homogeneous mixture
of two or more substances, consisting of ions or molecules. A
solution can be a solid, liquid, or gas. A solution results from
the combination of a solute and a solvent. A solute is, in the case
of a gas or solid dissolved in liquid, the gas or solid, but in
other cases it is the part that has the smaller amount. A solvent
is, in the case of a gas or solid dissolved in liquid, the liquid,
but in other cases it is the part that has the larger amount. In
the example concerning the salt, the solvent would be water and the
salt would be the solute.
So that we can understand the concept of solubility,
let's consider the process of dissolving sodium chloride in water.
We know that NaCl is an ionic compound, and that it dissolves in
water as Na+ and Cl- ions. When we mix 50
grams of salt in 100 mL of water we find something cool going on.
The sodium and chloride ions leave the surface of the crystal and
enter into the solution. These ions then move about at random in
the solution and occasionally bump into another crystal and stick,
returning to their crystalline state. As time passes, more sodium
chloride continues to dissolve into the solution, which means that
the ion concentration increases. This means that eventually more
ions are going to bump into each other and return to their
crystalline state. Over time, a dynamic equilibrium will be reached
in which the rate at which ions leave the crystals is equivalent to
the rate at which ions collide to form a crystal.
At this equilibrium, no more salt appears to
dissolve. We have reached what we call a saturated solution. A
saturated solution is a solution that is in equilibrium with
respect to a given dissolved substance. An unsaturated solution is
a solution that is not in equilibrium with respect to given
dissolved substance, leaving room for more substance to dissolve.
The solubility of a substance is the amount that dissolves in a
given quantity of water at a given temperature to give a saturated
solution. Sometimes, through special circumstances we can obtain a
supersaturated solution. A supersaturated solution is a solution
that contains more dissolved solute than is normally possible at
that temperature.
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