bronsted-lowery concept of acids and bases

The Bronsted-Lowery concept of acids and bases is that acid-base reactions can be seen as proton-transfer reactions. This results in acids and bases being able to be defined in terms of this proton (H+) transfer. According to the Bronsted-Lowery concept, acids donate a proton in a proton-transfer reactions. Bases accept the proton in a proton-transfer equation. As an example, lets look at the reaction of hydrochloric acid with ammonia. When we write it as an ionic equation we get:

H3O+(aq) + Cl-(aq) + NH3(aq) -> H2O(l) + NH4+(aq) + Cl-(aq)

reaction of hydrochloric acid with ammonia


which reduces to:
H3O+(aq) + NH3(aq) -> H2O(l) + NH4+(aq)

reduced reaction of hydrochloric acid with ammonia


because there is a Cl-(aq), on each side. We now have the net ionic equation after we cancel out the "spectator ions"(Cl-).



What happens in this reaction in aqueous solution is that a proton is transferred from H3O+ to NH3. This results in H3O+ losing a (H+), resulting in H2O. The NH3 gains the transferred proton, resulting in NH4+. We call H3O+ the proton donor, or acid. We call NH3 the proton acceptor, or base



The Bronsted-Lowery concept defines something as either an acid or base depending on its function in the acid-base (proton transfer) reaction. Some things can act as either an acid or a base. These are called amphiprotic species, they can either lose or gain a proton, depending on the other reactant. An example of an amphiprotic species would be:

HCO3-.

example of an amphiprotic species


In the presence of OH-, it acts as an acid. In the presence of HF it acts as a base. Water is also amphiprotic, as are most anions with ionizable hydrogens and certain solvents. Water as an amphiprotic species is very important to the acid-base reactions.



In the Bronsted-Lowery concept we have found that:

  • A base is a species that accepts protons, while an acid is a species that donates protons.
  • Acids and bases can be ions as well as molecular substances.
  • Some species can act as either acids or bases, depending on what the other reactant is.