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bronsted-lowery concept of acids and bases
The Bronsted-Lowery concept of acids and bases is
that acid-base reactions can be seen as proton-transfer reactions.
This results in acids and bases being able to be defined in terms
of this proton (H+) transfer. According to the
Bronsted-Lowery concept, acids donate a proton in a proton-transfer
reactions. Bases accept the proton in a proton-transfer equation.
As an example, lets look at the reaction of hydrochloric acid with
ammonia. When we write it as an ionic equation we get:
| H3O+(aq) +
Cl-(aq) + NH3(aq) -> H2O(l) +
NH4+(aq) + Cl-(aq) |
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reaction of hydrochloric acid with
ammonia
which reduces to:
| H3O+(aq) +
NH3(aq) -> H2O(l) +
NH4+(aq) |
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reduced reaction of hydrochloric acid with
ammonia
because there is a Cl-(aq), on each side. We now have
the net ionic equation after we cancel out the "spectator
ions"(Cl-).
What happens in this reaction in aqueous solution is that a proton
is transferred from H3O+ to NH3.
This results in H3O+ losing a
(H+), resulting in H2O. The NH3
gains the transferred proton, resulting in
NH4+. We call H3O+ the
proton donor, or acid. We call NH3 the proton acceptor,
or base
The Bronsted-Lowery concept defines something as either an acid or
base depending on its function in the acid-base (proton transfer)
reaction. Some things can act as either an acid or a base. These
are called amphiprotic species, they can either lose or gain a
proton, depending on the other reactant. An example of an
amphiprotic species would be:
example of an amphiprotic
species
In the presence of OH-, it acts as an acid. In the
presence of HF it acts as a base. Water is also amphiprotic, as are
most anions with ionizable hydrogens and certain solvents. Water as
an amphiprotic species is very important to the acid-base
reactions.
In the Bronsted-Lowery concept we have found that:
- A base is a species that accepts protons,
while an acid is a species that donates protons.
- Acids and bases can be ions as well as
molecular substances.
- Some species can act as either acids or bases,
depending on what the other reactant is.
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